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Chemistry Concept

Redox reaction

Transformation involving changes in oxidation states.

Close-up view of laboratory equipment with a flask, test tubes containing colored liquids, and a Petri dish with a spatula containing black powder
Properties and conditions
OxidationLoss of electrons in redox accounting
ReductionGain of electrons in redox accounting
Must conserveMass and charge

Definition and context

A redox reaction combines oxidation and reduction. In terms of electron accounting, one species gives up electrons and another receives them. Oxidation states help track this accounting, although they do not always represent full physical charges within a molecule.

The concept is useful when we want to explain where a cell’s current comes from. Separating processes and connecting a circuit makes it possible to organize a chemical transformation to obtain an electrical output. To analyze a specific reaction, we need the species and conditions, as well as conservation of mass and charge. A correctly balanced equation is a starting point: by itself, it does not tell us how fast the process occurs or how long a real device will last.

What we know and its limits

Introductory reference sheet. Properties and applications depend on measurement conditions; consult the sources before making comparisons.

Follow the evidence

The original sources for exploring this explanation and its limits.

  1. Chemistry 2e · Redox Reactions OpenStax · Rice University
    Oxidation, reduction, and electron balancing.
  2. Chemistry 2e · Potential and Free Energy OpenStax · Rice University
    Relationship between electrochemical potential and energy.
Image credits

Photo by Ron Lach on Pexels · Original source · Pexels License

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